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International Journal of Latest Research in Science and Technology

DOI:10.29111/ijlrst   ISRA Impact Factor:3.35

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SYNTHESIS AND OPTICAL PROPERTIES OF THIOGLYCOL-CAPPED CdSe QUANTUM DOTS EMBEDDED IN TiO2 FILMS FOR SOLAR CELL APPLICATIONS

Research Paper Open Access

International Journal of Latest Research in Science and Technology Vol.4 Issue 3, pp 34-38,Year 2015

SYNTHESIS AND OPTICAL PROPERTIES OF THIOGLYCOL-CAPPED CDSE QUANTUM DOTS EMBEDDED IN TIO2 FILMS FOR SOLAR CELL APPLICATIONS

H. T. Tung and Nguyen Thanh Nguyen

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Received : 19 May 2015; Accepted : 12 June 2015 ; Published : 30 June 2015

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Abstract

CdSe quantum dots have been prepared via a colloidal route using Mercaptoethanol (Thioglycol) (HOCH2CH2SH) as a capping agent. The stability of the particles in solution and embedded in TiO2 matrices has been followed by optical absorption and photoluminescence. Both the size and the size distribution of the particles are well controlled by ratio mole and temperature, thus allowing a tunable emission. Room temperature photoluminescence (PL) studies are reported, the band is assigned to recombination through defect states, whose energy depends on the nanocrystallite size and so depend the optical band gap on the nanocrystallite. X-ray, UV-Vis spectroscopies, and TEM have been used to characterize colloidal CdSe. With CdSe nanoparticles as seeds on TiO2 film, a highly efficient of CdSe/TiO2 thin films photoanode was prepared by dip coating deposition technique.

Key Words   
nanocrystals; thin film; defect states; CdSe nanocrystals; TiO2, solar cell.
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References
  1. C. B, Kagan. C. R and Bawendi. M. G, Annu. Rev. Mater. Sci. 30,545 (2000).
  2. Q, Dong. Y.J, Deng. Z.X, Li. Y.D. Inorg. Chem. 41 (2002) 5249.
  3. M.H, Gao. L, Am. J.Ceram.Soc.88 (2005) 1643.
  4. L.F, Lam. Y.M, J. Colloid Interface Sci. 316 (2007) 771.
  5. M, Giorgio. S, Pileni. M.P.Adv. Mater. 14 (2002) 1084.
  6. (a) Alivisatos.A.P. Nat. Biotechnol,2004, 22,47; (b) Jaiswal. J. K and Simon. S. M.Trends Cell Biol, 2004, 14, 497.
  7. J, Narayan. K. S, Kuruvilla. B. A, Murthy. G. L and Sarma.D.D. Appl. Phys. Lett. 1998, 72, 1335.
  8. (a) Koktysh. D. S, Gaponik. N, Reufer. M. Crewett. J, Scherf. U, Eychmuller. A, Lupton. J. M, Rogach. A. L and Feldmann. J, ChemPhysChem, 2004, 5, 1435; (b) Gao. M.Y, Lesser. C, Kirstein. S, Mo. H. Rogach. A. L and Weller. H. J. Appl. Phys.2000,87,2297.
  9. V. I, Mikhailovsky. A. A, Xu. S, Malko. A, Hollingsworth. J. A, Leatherdale. C. A, Eisler. H. J and Bawendi. M. G. Science. 2000, 290, 314.
  10. A.L, Rosen.M, Kuno.M, Nirmal.M, Norris.d.J and Bawendi.M.Phys. Re .B 1996,54, 4843.
  11. M, Lee.J.K, Dabbousi.B.O, Mikulec.F.V, Bawendi.M.G.J.Chem.Phys.1997, 106, 9869.
  12. V.I, Mikhailovsky.A.A, Xu.S, Malko.A, Hollingsworth.J.A, Leatherdale.C.A, Eisler.H.J and Bawendi.M.G. Science.290, 314 (2000).
  13. Iván Mora-Seró, Vlassis Likodimos, Sixto Giménez, Eugenia Martínez-Ferrero, Josep Albero, Emilio Palomares, Athanassios G. Kontos, Polycarpos Falaras, and Juan Bisquert (2010), “Regeneration of CdSe Quantum Dots by Ru Dye in Sensitized TiO2 Electrodes”, J. Phys. Chem. C XXXX, xxxx, 000.
  14. Jin Young Kim, Sung Bum Choi, Jun Hong Noh, Sung HunYoon, Sangwook Lee, Tae Hoon Noh, Arthur J. Frank, and Kug Sun Hong (2009), “Synthesis of CdSe-TiO2 Nanocomposites and Their Applications to TiO2 Sensitized Solar Cells”, Langmuir,  American Chemical Society
  15. Kevin Tvrdy and Prashant V. Kamat (2009), “Substrate Driven Photochemistry of CdSe Quantum Dot Films: Charge Injection and Irreversible Transformations on Oxide Surfaces”, Phys. Chem. A , 113, 3765–3772.
To cite this article

H. T. Tung and Nguyen Thanh Nguyen , " Synthesis And Optical Properties Of Thioglycol-capped Cdse Quantum Dots Embedded In Tio2 Films For Solar Cell Applications ", International Journal of Latest Research in Science and Technology . Vol. 4, Issue 3, pp 34-38 , 2015


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