eISSN:2278-5299

International Journal of Latest Research in Science and Technology

DOI:10.29111/ijlrst   ISRA Impact Factor:3.35

A News Letter Sign UP!
HARVESTING LIGHT ENERGY WITH CdSe/ CdSe (SILAR) /ZnS (SILAR) NANOCRYSTALS MOLECULARLY LINKED TO MESOSCOPIC TiO2 FILMS FOR QUANTUM DOT SOLAR CELLS

Research Paper Open Access

International Journal of Latest Research in Science and Technology Vol.3 Issue 6, pp 33-36,Year 2014

HARVESTING LIGHT ENERGY WITH CDSE/ CDSE (SILAR) /ZNS (SILAR) NANOCRYSTALS MOLECULARLY LINKED TO MESOSCOPIC TIO2 FILMS FOR QUANTUM DOT SOLAR CELLS

H. T. Tung

Correspondence should be addressed to :

Received : 14 December 2014; Accepted : 24 December 2014 ; Published : 31 December 2014

Share
Download 125
View 180
Article No. 10418
Abstract

On paper, we have prepared TiO2/MPA/CdSe/ZnS by Successive ionic layer adsorption and reaction (SILAR). The results show that a significant improvement of the light to electric power conversion efficiency of quantum dot sensitized solar cells with a polysulfide electrolyte which can be achieved as using bi functional surface modifiers (SH-R-COOH, Mercaptopropionic acid (MPA)). The injected charge carriers in a CdSe-modified TiO2/MPA film can be collected at a conducting electrode to generate a photocurrent. The TiO2/MPA/CdSe/ZnS composite, employed as a photo anode in a photo electrochemical cell, exhibits a photon to charge carrier generation efficiency η, the short circuit current JSC, open circuit voltage VOC, and fill factor FF correspond to 0.909 %, 6.67 mA/cm2, 0.43 V, 0.31.

Key Words   
Defect states, Solar cell, SILAR
Copyright
References
  1. Zi-Xia Li, Yu-Long Xie, Hua Xu, Tian-Ming Wang, Zhu-Guo Xu, Hao-Li Zhang. “Expanding the photo response range of TiO2 nanotube arrays by CdS/CdSe/ZnS quantum dots co-modification”. Photochem. Photobiol. A. 224 (2011) 25– 30.
  2. B. Sambur, B. A. Parkinson. “CdSe/ZnS core/shell quantum dot sensitization of low index TiO(2) single crystal surfaces”. J. Am. Chem. Soc. 132 (2010) 2130–2131.
  3. H. Chen, L. Gao. “Synthesis and characterization of CdSe nanorods using a novel micro emulsion method at moderate temperature”. J. Am. Ceram. Soc. 88 (2005) 1643.
  4. F. Xi, Y. M. Lam. “Synthesis and Characterization of CdSe Nanorods using a Novel Micro emulsion Method at Moderate temperature”. Colloid Interface. Sci. 316 (2007) 771.
  5. F. Hossain, S. Biswas, Z. H. Zhang, T. Takahashi. “Bubble-like CdSe nanoclusters sensitized TiO2 nanotube arrays for improvement in solar cell”. J. Photochem. Photobiol. A 217 (2011) 68–75.
  6. F. Gao, W.T. Sun, G. Ai, L. M. Penga. “Photoelectric Performance of TiO2 Nanotube Array Photo electrodes Co sensitized with CdS/CdSe Quantum Dots”. Appl. Phys. Lett. 96 (2010) 153104–153106.
  7. Zion Tachan, Menny Shalom, Idan Hod, Sven R€ uhle, Shay Tirosh, and Arie Zaban. “PbS as a Highly Catalytic Counter Electrode for Polysulfide-Based Quantum Dot Solar Cells”. Phys. Chem. C (2011), 115, 6162–6166.
  8. Granot, F. Patolsky, I. J. Willner. “Electrochemical Assembly of a CdS Semiconductor Nanoparticle Monolayer on Surfaces: Structural Properties and Photo electrochemical Applications”. Phys. Chem. B 2004, 108, 5875. 5881.
  9. V. Kamat, S. Barazzouk, S. Hotchandani. Quantum Dot Solar Cells. “Tuning Photoresponse through Size and Shape Control of CdSe−TiO Architecture”. Chem. Int. Ed. 2002, 41, 2764. 2767.
  10. Zayats, A. B. Kharitonov, S. P. Pogorelova, O. Lioubashevski, E. Katz, I. J. Willner. “Probing photo electrochemical processes in Au-CdS nanoparticle arrays by surface plasmon resonance: Application for the detection of acetylcholine esterase inhibitors”. Am. Chem. Soc 2003, 125, 16006. 16014.
  11. Grätzel. “Review article Photo electrochemical cells”. Nature 414 (2001) 338–344.
  12. V. Chris, J. Neugebauer. “Universal alignment of hydrogen levels in semiconductors, insulators and solutions”. Nature 423 (2003) 626–628.
  13. L. Lee, Y. S. Lo. “CdSe quantum dot co-sensitized TiO2 photoelectrodes: particle size dependent properties”. Adv. Funct. Mater. 19 (2009) 604–609.
  14. Kongkanand, K. Tvrdy, K. Takechi, M. Kuno, P.V. Kamat. “Nanowire-quantum-dot solar cells and the influence of nanowire length on the charge collection efficiency”. J. Am. Chem. Soc. 130 (2008) 4007–4015.
  15. L. Efros, M. Rosen, M. Kuno, M. Nirmal, D. Norris. J and Bawendi. M. “Band-edge exciton in quantum dots of semiconductors with a degenerate valence band: dark and bright exciton states”. Phys. Rev. B. 1996, 54, 4843.
  16. E. Brus. “Electron–electron and electron‐hole interactions in small semiconductor crystallites: The size dependence of the lowest excited electronic state”. J. Chem. Phys. 1984, 80, 4403.
To cite this article

H. T. Tung , " Harvesting Light Energy With Cdse/ Cdse (silar) /zns (silar) Nanocrystals Molecularly Linked To Mesoscopic Tio2 Films For Quantum Dot Solar Cells ", International Journal of Latest Research in Science and Technology . Vol. 3, Issue 6, pp 33-36 , 2014


Responsive image

MNK Publication was founded in 2012 to upholder revolutionary ideas that would advance the research and practice of business and management. Today, we comply with to advance fresh thinking in latest scientific fields where we think we can make a real difference and growth now also including medical and social care, education,management and engineering.

Responsive image

We offers several opportunities for partnership and tie-up with individual, corporate and organizational level. We are working on the open access platform. Editors, authors, readers, librarians and conference organizer can work together. We are giving open opportunities to all. Our team is always willing to work and collaborate to promote open access publication.

Responsive image

Our Journals provide one of the strongest International open access platform for research communities. Our conference proceeding services provide conference organizers a privileged platform for publishing extended conference papers as journal publications. It is deliberated to disseminate scientific research and to establish long term International collaborations and partnerships with academic communities and conference organizers.