eISSN:2278-5299

International Journal of Latest Research in Science and Technology

DOI:10.29111/ijlrst   ISRA Impact Factor:3.35

A News Letter Sign UP!
EFFECT OF CROSS-LINKING ON ADHESION PROPERTY OF BENZOYL-PEROXIDE-CURED EPOXIDIZED NATURAL RUBBER (ENR 25)/ ACRYLONITRILE-BUTADIENE RUBBER (NBR) BLEND ADHESIVE

Research Paper Open Access

International Journal of Latest Research in Science and Technology Vol.3 Issue 4, pp 104-108,Year 2014

EFFECT OF CROSS-LINKING ON ADHESION PROPERTY OF BENZOYL-PEROXIDE-CURED EPOXIDIZED NATURAL RUBBER (ENR 25)/ ACRYLONITRILE-BUTADIENE RUBBER (NBR) BLEND ADHESIVE

B. T. Poh, B. Azahari, K.W. Soo

Correspondence should be addressed to :

Received : 30 June 2014; Accepted : 18 July 2014 ; Published : 31 August 2014

Share
Download 125
View 179
Article No. 10363
Abstract

The effect of benzoyl peroxide loading on the adhesion properties of cross-linked epoxidized natural rubber (ENR 25) / acrylonitrile-butadiene rubber (NBR) blend adhesives were studied using coumarone indene resin resin and toluene as tackifier and solvent respectively. Throughout the study, benzoyl peroxide was used to crosslink the rubber blend adhesive with the loading from 1 to 5 parts per hundred part of rubber (phr) at 80ºC for 30 min. The SHEEN hand coater was used to coat the adhesive on polyethylene terephthalate (PET) at 30 µm and 120 µm coating thickness. The adhesion properties were determined by a Lloyd adhesion tester operating at 30 cm min−1. Results shows that the loop tack and peel strength of the ENR 25/NBR adhesive pass through a maximum value at 2 phr of benzoyl peroxide. This observation is attributed to the optimum crosslinking of rubber blend chains where optimum cohesive and adhesive strength is obtained. The shear strength, however, increases steadily with increasing benzoyl peroxide loading due to the steady increase in the cohesive strength of crosslinked rubber blend adhesive. In all cases, the adhesion properties of adhesives increase with increase in coating thickness.

Key Words   
Adhesion; Adhesive; Rubber; Crosslinking; Tackifier
Copyright
References
  1. K. De and J.R. White, Rubber technologist's handbook, Vol. 1, Rapra Publishing – Shawbury, 2001.
  2. Ismail, Z. Ahmad and F. W. Yew, “Effect of monomer composition on adhesive performance for waterborne acrylic pressure-sensitive adhesives,” Journal of Physical Science, Vol. 22, pp. 51–63, 2011.
  3. Fujita, A. Takemura, H. Ono, M. Kajiyama, S. Hayashi, M. Mizumachi, “Effects of miscibility and viscoelasticity on shear creep resistance of natural-rubber-based pressure-sensitive adhesives,” Journal of Applied Polymer Science, Vol. 75, pp. 1535-1545, 2000.
  4. M. Taghizadeh and D. Ghasemi, “Synthesis and optimization of a four-component acrylic-based copolymer as pressure sensitive adhesive,” Iranian Polymer Journal, Vol. 19, pp. 343-352, 2010.
  5. Mou, F. Shen, Y. Liu, C. Wu, W. Guo, “ A novel nitrile butadiene rubber/zinc chloride composite: coordination reaction and miscibility,” European Polymer Journal, Vol. 48, pp. 857-865, 2012.
  6. Iyer, K. Li, P. Mallya, W. Wang, “Synthesis of benzocyclobutenone containing polymers for UV curable pressure sensitive adhesive applications.” Arkivoc, Vol.13, pp. 29-36, 2005.
  7. T. Poh and S. K. Cheong, “Adhesion behavior of natural rubber‐based adhesives crosslinked by benzoyl peroxide,” Journal of Applied Polymer Science, Vol. 124, pp. 1031-1035, 2012.
  8. T. Poh and N. H. Suid, “Dependence of adhesion properties of cross-linked epoxidized natural rubber (ENR 25)-based pressure-sensitive adhesives on benzoyl peroxide loading in the presence of gum rosin and petroresin tackifiers,” The Journal of Adhesion, Vol. 90, pp. 899-911, 2013.
  9. T. Poh, and C. H. Lim, “Effect of cross-linking on adhesion property of benzoyl-peroxide-cured epoxidized natural rubber (ENR 50) adhesives,” Journal of Elastomers and Plastics, Vol. 46, pp. 187-198, 2014.
  10. T. Poh and Y. Y. Teh, “Dependence of adhesion property of epoxidized natural rubber (ENR 25)/ethylene-propylene-diene rubber blend adhesives crosslinked by benzoyl peroxide,” Journal of Coatings, 2014.
  11. T. Poh and J. Lamaming, “Effect of testing rate on adhesion properties of acrylonitrile-butadiene rubber/standard malaysian rubber blend-based pressure-sensitive adhesive,” Journal of Coatings, 2013.
  12. Pizzi and K. L. Mittal, Handbook of adhesive technology, ed. 2nd, CRC Press – New York, 2003.
  13. C. Leong, L. M. S. Lee and S. N. Gan, “The viscoelastic properties of natural rubber pressure-sensitive adhesive using acrylic resin as a tackifier,” Journal of Applied Polymer Science, Vol. 88, pp. 2118-2123, 2003.
  14. T. Poh and Y. Y. Teh, “Effect of blend ratio and testing rate on the adhesion properties of epoxidized natural rubber (ENR 50)/acrylonitrile-butadiene rubber (NBR) blend adhesive,” The Journal of Adhesion, Vol. 90, 2013.
  15. Satas, Handbook of pressure sensitive adhesive technology, Van Nostrand Reinhold– New York, 1982.
  16. Pang, C. M. Ryu and H. I. Kim, “Improvement in wettability of pressure-sensitive adhesive on silicon wafer using crosslinking agent with siloxane groups.” Journal of Applied Polymer Science, Vol. 129, pp. 276-281, 2013.
  17. H. Lee, Adhesive bonding, Plenum Press – New York, 1991.
  18. Skeist, Handbook of adhesives, ed. 3rd, Van Nostrand Reinhold – New york, 1990.
To cite this article

B. T. Poh, B. Azahari, K.W. Soo , " Effect Of Cross-linking On Adhesion Property Of Benzoyl-peroxide-cured Epoxidized Natural Rubber (enr 25)/ Acrylonitrile-butadiene Rubber (nbr) Blend Adhesive ", International Journal of Latest Research in Science and Technology . Vol. 3, Issue 4, pp 104-108 , 2014


Responsive image

MNK Publication was founded in 2012 to upholder revolutionary ideas that would advance the research and practice of business and management. Today, we comply with to advance fresh thinking in latest scientific fields where we think we can make a real difference and growth now also including medical and social care, education,management and engineering.

Responsive image

We offers several opportunities for partnership and tie-up with individual, corporate and organizational level. We are working on the open access platform. Editors, authors, readers, librarians and conference organizer can work together. We are giving open opportunities to all. Our team is always willing to work and collaborate to promote open access publication.

Responsive image

Our Journals provide one of the strongest International open access platform for research communities. Our conference proceeding services provide conference organizers a privileged platform for publishing extended conference papers as journal publications. It is deliberated to disseminate scientific research and to establish long term International collaborations and partnerships with academic communities and conference organizers.